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    Fermi resonance - Wikipedia

    A Fermi resonance is the shifting of the energies and intensities of absorption bands in an infrared or Raman spectrum. It is a consequence of quantum-mechanical wavefunction mixing. The phenomenon was first explained by the Italian physicist Enrico Fermi. See more

    Two conditions must be satisfied for the occurrence of Fermi resonance:
    • The two vibrational modes of a molecule transform according … See more

    Ketones
    High-resolution IR spectra of most ketones reveal that the "carbonyl band" is split into a doublet. The peak separation is usually only a few cm . This splitting arises from the mixing of νCO and the overtone of HCH bending modes. See more

     
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