A total of 76 teams from 52 of the 54 UEFA member associations participated in the 2013–14 UEFA Champions League (the exceptions being Liechtenstein, which do not organise a domestic league, and Gibraltar, which started participating in the 2014–15 season after being admitted as a UEFA member in May 2013). [5][6] The association ranking based on the UEFA country coefficients was used to determine the number of participating teams for each association: [7]

• Associations 1–3 each have four teams qualify.
• Associations 4–6 each have three teams qualify.
• Associations 7–15 each have two teams qualify.
• Associations 16–53 (except Liechtenstein) each have one team qualify.